Yes. Click the settings button on the Tray Selector printer setup utility and select the profile from which you want to print an envelope. Click the button called “Envelopes”. The dialogue box shown below will appear. Check the box to enable envelope printing, and select the printer to which you want the envelope to be sent. Now, when the profile button is pressed, it will also show the normal Word envelopes dialogue, allowing you to print an envelope too. See the help page for more details.